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戊酸酯类燃料分子制备研究进展

发表时间:2016-07-15  浏览量:5905  下载量:3686
全部作者: 刘新鑫,严龙,陈蒙远,傅尧,郭庆祥
作者单位: 中国科学技术大学化学与材料科学学院,安徽省生物质洁净能源重点实验室
摘 要: 随着化石燃料的日益枯竭,从可再生生物质资源制备液体燃料吸引了人们的关注。通过生物质平台分子乙酰丙酸(levulinic acid,LA)催化转化为燃料分子更是一个热点课题。与传统的生物质基燃料分子(γ-戊内酯、甲基四氢呋喃、乙醇等)相比,戊酸酯在性质上更易与现有的化石燃料兼容。由乙酰丙酸制备戊酸(酯)已开发出多种催化体系,通过对戊酸(酯)的合成方法归纳总结,为探索更高效的戊酸(酯)的合成方法提供参考。
关 键 词: 有机化学;戊酸;综述;非均相催化
Title: Progress in the studies of production of valerate esters
Author: LIU Xinxin, YAN Long, CHEN Mengyuan, FU Yao, GUO Qingxiang
Organization: Anhui Province Key Laboratory of Biomass Clean Energy, School of Chemistry and Materials Science, University of Science and Technology of China
Abstract: With the increasing depletion of fossil resources, preparing the liquid fuel from renewable biomass resources attracts people’s attention. The catalytic conversion of fuel molecules by biomass platform molecule levulinic acid (LA) is a hot topic. Comparison with the traditional biomass-based fuel molecules (γ-valerolactone, methyl tetrahydrofuran, ethanol, etc.), the property of valerate esters is more compatible than existing fossil fuels. Many processes for conversing LA into valerate esters have been reported. The summary of the valerate esters synthesis provides a reference for exploring more efficient synthesis method to valerate esters.
Key words: organic chemistry; valeric acid; review; heterogeneous catalysis
发表期数: 2016年7月第13期
引用格式: 刘新鑫,严龙,陈蒙远,等. 戊酸酯类燃料分子制备研究进展[J]. 中国科技论文在线精品论文,2016,9(13):1281-1287.
 
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