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具有“柱-层”结构的三维配位聚合物{[Cu2(bpta)(4,4’-bipy)]·(H2O)3}n的合成与结构表征
发表时间:2013-04-15 浏览量:1594 下载量:409
| 全部作者: | 吕迎彬,张大帅,田丹,常泽 |
| 作者单位: | 南开大学化学学院,天津市金属与分子基材料化学重点实验室 |
| 摘 要: | 采用水热法以2,2’,6,6’-联苯四甲酸(H4bpta)和4,4’-联吡啶(4,4’-bipy)为配体与硝酸铜反应合成一个新型的具有“柱-层”结构的配位聚合物{[Cu2(bpta)(4,4’-bipy)]·(H2O)3}n,利用红外光谱(infrared spectroscopy, IR)、元素、热重及X射线单晶结构分析对其进行表征,证明了它的结构。 |
| 关 键 词: | 配位化学;配位聚合物;“柱-层”结构;水热合成 |
| Title: | Synthesis and structure characterization of 3D pillared {[Cu2(bpta)(4,4’-bipy)]·(H2O)3}n with metal-organic frameworks |
| Author: | LV Yingbin, ZHANG Dashuai, TIAN Dan, CHANG Ze |
| Organization: | College of Chemistry, Nankai University, Tianjin Key Lab of Metal and Molecule-based Material Chemistry |
| Abstract: | With the ligands of H4bpta=1,1’-biphenyl-2,2’,6,6’-tetracarboxylic acid and 4,4’-bipy = 4,4’-bipyridine, a pillar-layer structure coordination compound of the formulas {[Cu2(bpta)(4,4’-bipy)]·(H2O)3}n was synthesized using hydrothermal method and Cu(NO3)2·3H2O reaction. Furthermore, its structure was characterized by infrared spectroscopy (IR), element analysis, thermalgravimetric analyses and X-ray single-crystal diffraction. |
| Key words: | coordination chemistry; coordination polymer; pillar-layer structure; hydrothermal synthese |
| 发表期数: | 2013年4月第7期 |
| 引用格式: | 吕迎彬,张大帅,田丹,等. 具有“柱-层”结构的三维配位聚合物{[Cu2(bpta)(4,4’-bipy)]·(H2O)3}n的合成与结构表征[J]. 中国科技论文在线精品论文,2013,6(7):611-615. |
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