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具有“柱-层”结构的三维配位聚合物{[Cu2(bpta)(4,4’-bipy)]·(H2O)3}n的合成与结构表征

发表时间:2013-04-15  浏览量:1327  下载量:358
全部作者: 吕迎彬,张大帅,田丹,常泽
作者单位: 南开大学化学学院,天津市金属与分子基材料化学重点实验室
摘 要: 采用水热法以2,2’,6,6’-联苯四甲酸(H4bpta)和4,4’-联吡啶(4,4’-bipy)为配体与硝酸铜反应合成一个新型的具有“柱-层”结构的配位聚合物{[Cu2(bpta)(4,4’-bipy)]·(H2O)3}n,利用红外光谱(infrared spectroscopy, IR)、元素、热重及X射线单晶结构分析对其进行表征,证明了它的结构。
关 键 词: 配位化学;配位聚合物;“柱-层”结构;水热合成
Title: Synthesis and structure characterization of 3D pillared {[Cu2(bpta)(4,4’-bipy)]·(H2O)3}n with metal-organic frameworks
Author: LV Yingbin, ZHANG Dashuai, TIAN Dan, CHANG Ze
Organization: College of Chemistry, Nankai University, Tianjin Key Lab of Metal and Molecule-based Material Chemistry
Abstract: With the ligands of H4bpta=1,1’-biphenyl-2,2’,6,6’-tetracarboxylic acid and 4,4’-bipy = 4,4’-bipyridine, a pillar-layer structure coordination compound of the formulas {[Cu2(bpta)(4,4’-bipy)]·(H2O)3}n was synthesized using hydrothermal method and Cu(NO3)2·3H2O reaction. Furthermore, its structure was characterized by infrared spectroscopy (IR), element analysis, thermalgravimetric analyses and X-ray single-crystal diffraction.
Key words: coordination chemistry; coordination polymer; pillar-layer structure; hydrothermal synthese
发表期数: 2013年4月第7期
引用格式: 吕迎彬,张大帅,田丹,等. 具有“柱-层”结构的三维配位聚合物{[Cu2(bpta)(4,4’-bipy)]·(H2O)3}n的合成与结构表征[J]. 中国科技论文在线精品论文,2013,6(7):611-615.
 
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