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含有富勒烯[C60]液晶材料的设计与应用

发表时间:2013-04-15  浏览量:1404  下载量:621
全部作者: 张小艳,顾艳,闫红红,张盼,李超,屠迎锋
作者单位: 苏州大学材料与化学化工学部
摘 要: 含富勒烯的液晶材料是一类既具有富勒烯优异的光电性质又具有液晶的自组织及易加工性能的新型材料。富勒烯液晶分子的设计主要包括直接合成长径比或径厚比大于4的分子,和通过分子自组装得到长径比或径厚比大于4的超分子2种方法。通过合理的分子设计,可将功能性基团,如:二茂铁、树枝状分子基元、手性基元以及酞菁等引入到含有富勒烯的液晶分子中,拓展富勒烯液晶材料的应用领域。
关 键 词: 高分子化学;富勒烯液晶;综述;自组织;自组装
Title: Design and application of fullerene-based liquid crystals
Author: ZHANG Xiaoyan, GU Yan, YAN Honghong, ZHANG Pan, LI Chao, TU Yingfeng
Organization: College of Chemistry, Chemical Engineering and Materials Science, Soochow University
Abstract: Fullerene-based liquid crystals are a new kind of materials with excellent electrochemical, photophysical properties of fullerenes and self-organization, processible properties of liquid crystals. The design of fullerene liquid crystals includes two ways: direct synthesis of molecular liquid crystals with the molecular aspect ratio larger than 4, and supramolecular liquid crystals with the molecular aspect ratio larger than 4 through self-assemble or self-organize of fullerene molecules. Functional groups such as ferrocene, dendron, chiral and phthalocyanine groups can be introduced into fullerene-based liquid crystals by careful molecular design, which expands the application field of fullerene-based liquid crystals.
Key words: polymer chemistry; fullerene-based liquid crystals; review; self-organization; self-assembly
发表期数: 2013年4月第7期
引用格式: 张小艳,顾艳,闫红红,等. 含有富勒烯[C60]液晶材料的设计与应用[J]. 中国科技论文在线精品论文,2013,6(7):616-624.
 
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