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过渡金属催化芳环上官能团转化研究进展

发表时间:2015-02-15  浏览量:1422  下载量:620
全部作者: 石亮亮,付华
作者单位: 清华大学化学系, 生命有机磷化学及化学生物学教育部重点实验室
摘 要: 芳基上官能团的转化是化学领域中一个重要的研究方向,过渡金属催化芳环上的官能团转化取得了显著的成果。主要从过渡金属催化卤代芳烃、酚、芳胺、芳基叠氮、硝基苯衍生物、芳基硼酸酯的合成6个方面综述了过渡金属催化芳环上官能团转化的最新研究进展,并且展望了这些方法的应用前景,以期获得更加简单、高效、无毒的催化剂。
关 键 词: 配位化学;芳基化合物;综述;官能团转化;过渡金属催化
Title: Advanced in transition metal-catalyzed transformations offunctional groups on aromatic rings
Author: SHI Liangliang, FU Hua
Organization: Key Lab of Bioorganic Phosphorus Chemistry & Chemical Biology, Ministry of Education, Department of Chemistry, Tsinghua University
Abstract: Transformation of the functional groups is an important field of chemistry research. Transition metal-catalyzed conversion reaction of functional group on aromatic ring had achieved remarkable results. This article summarized the six aspects of transition metal catalyzed conversion of functional groups on the aromatic ring from the transition metal-catalyzed synthesis halogenated aromatic hydrocarbons, phenols, aromatic amines, aryl azide, nitrobenzene derivatives to aryl boronic acid ester. This review focused on the recent advance in transition metal-catalyzed transformation of the functional groups and discussed the application prospect of these methods to obtain more simple, efficient and less toxic catalysts.
Key words: coordination chemistry; aromatic compounds; review; functional group transformation; transition metal-catalyzed
发表期数: 2015年2月第3期
引用格式: 石亮亮,付华 . 过渡金属催化芳环上官能团转化研究进展 [J]. 中国科技论文在线精品论文,2015,8(3):201-212.
 
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